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TitlePage   Preface   Contents    

Volcanic Events, pg. 2
Mount St. Helens History, pg. 3-15
Eyewitnesses, pg. 53-67
Absolute Times, pg. 81-82, 86
Activity Sequence, pg. 127-134
Gas Studies, pg. 190-191
Chemical Compositions, pg. 233-250
Ash Clouds, pg. 323-333
Blast Dynamics, pg. 379-400
Rapid Deposition, pg. 466-478
Phreatic Explosions, pg. 509-511
New Lava Dome, pg. 540-544
Ash-Fall Deposits, pg. 568-584
Water Chemistries, pg. 659-664
River Water Quality, pg. 719-731



THE 1980 ERUPTIONS OF MOUNT ST. HELENS, WASHINGTON

PROPERTIES OF GASES AND WATERS OF DEEP ORIGIN

NEAR MOUNT ST. HELENS

By I. BARNES, D. A. JOHNSTON, W. C. EVANS, T. S. PRESSER, R. H. MARINER, and L. D. WHITE


ABSTRACT

Fluids discharging from depth in the Mount St. Helens area include a metamorphic brine, as represented by Pigeon Springs water discharging from metavolcanic rocks to the west, CO2 from the mantle as represented by the CO2 well field at Klickitat, and CO2 from the breakdown of organic matter as represented by the gases from springs north and south of Mount St. Helens and in a pond in the April 1980 crater.
 

INTRODUCTION

Carbon dioxide (CO2) is a major gas component in some explosive eruptions (Johnston, 1980; Barnes and McCoy, 1979), in some hot springs (White and others, 1973; Mariner and others, 1975; Mariner and others, 1980), and in discharges from cold volcanic sources (Johnston, 1978, p. 78) and throughout the world in seismically active areas (Irwin and Barnes, 1980; Barnes and others, 1978).

As a guide to the interpretations of the 13C compositions referred to the well-known PDB standard, 13C values in the range + 3 to -- 3 per mil are typical of marine carbonates (Craig, 1953) and values of - 20 per mil and more depleted are typical of organic matter (Craig, 1953). Mantle-derived 13C lies in the range -- 5 to -8 per mil (Pineau and others, 1976; Moore and others, 1977). Meteoric water has isotopic compositions given by the equation (Craig, 1961) ------ where D and 18O are the deuterium and oxygen compositions in per mil relative to SMOW (standard mean ocean water).

Methods used for analyses of the waters are summarized by Presser and Barnes (1974). Gas samples were collected in evacuated glass sample tubes with high vacuum stopcocks and were analyzed with a gas chromatograph. Strontium carbonate samples were precipitated in the field and the CO2 subsequently evolved by treatment with H3PO4. All bicarbonate titrations were done in the field except for the water sample from the pre-May 18 crater, which was titrated in the laboratory. Isotope analyses were made by L. D. White in the laboratory of J. R. O'Neil.
 

FIELD RELATIONS

Soda Spring, Mount St. Helens, and Government Mineral Springs lie on a line (fig. 130) that extends south-southeast to Mount Hood. Water was collected on April 23, 1980, from a pond 15 m in diameter that occupied the bottom of the summit crater of Mount St. Helens. Gas escaping through the pond raised the surface as much as 15 cm about 2 m from the shore of the pond, and there was a strong odor of hydrogen sulfide (H2S) in the crater.

The sampled well at the Klickitat CO2 field, east of Government Mineral Springs, discharges irregularly, erupting CO2 and gas-laden water for 3 min at half-hour intervals. Pigeon Springs is to the west of Government Mineral Springs (fig. 130) and southwest of Mount St. Helens; the altered volcanic country rock consists of quartz, chlorite, calcite, and albite, as indicated by optical and X-ray study.
 

DISCUSSION

The isotopic compositions of the CO2-rich waters at Government Mineral Springs, Soda Spring, the Klickitat CO2 well, and water from the pond in the Mount St. Helens crater are all in the range of meteoric water (table 15 (ABOVE); fig. 131). None of them show the shift in 18O expected from water that has reacted with or exchanged isotopically with volcanic rocks (Craig, 1963). The water at Klickitat is relatively depleted in both 18O and D, because it is farther from the ocean along the path of air masses yielding precipitation.

The isotopic compositions of the CO2 being discharged show two sources. For the CO2 at Klickitat, 13C is -5.38 to -6.10 per mil, a value characteristic of CO2 from the mantle. The other CO2 discharges are more depleted in 13C, especially that from the crater pond (-19.53 per mil), probably due to decomposition of organic (woody) material incorporated in older subsurface volcanic rocks. From the pH and HCO3- values, the calculated CO2 pressure that would be in equilibrium with the dissolved CO2 is 0.05 atm, more than two orders of magnitude higher than the CO2 pressure in air.

In contrast to the CO2-rich meteoric waters at the above locations, nitrogen-rich nonmeteoric water discharges from Pigeon Springs. Neither the 18O nor the D concentrations at Pigeon Springs resemble those of local meteoric water, nor do the isotopic compositions plot on the meteoric water line (fig. 131). Pigeon Springs water resembles metamorphic waters of non-meteoric origin (White and others, 1973). In contrast to the complex chemistry of most metamorphic waters, Pigeon Springs water also resembles seawater that has reacted with rocks to lose Na and gain Ca, and its Cl concentration (22,000 mg/L) is similar to that of modern seawater (19,000 mg/L Cl). The negative D of Pigeon Springs water is at variance with this interpretation, however. All known silica-alumina hydrates are depleted in D relative to water they are in equilibrium with (Friedman and O'Neil, 1977, fig. 40), and if seawater of 0 per mil deuterium reacted to form chlorite, positive 6D values would result.

Although the origin of the saline water of Pigeon Springs is unclear, its relations to the minerals of the altered volcanic rock are known. The reaction states of Pigeon Springs water with respect to possible coexisting minerals were calculated (table 17) by computer (Kharaka and Barnes, 1973). The calculated states are from the equation where GR is the free-energy difference between the equilibrium state and the actual state, and R is the gas constant, T is the temperature (absolute), Q is the reaction quotient, and K is the equilibrium constant.

The states of reaction and the mineral composition of the altered volcanic rock at Pigeon Springs are compatible. The water is supersaturated with respect to the quartz, chlorite, albite, and calcite that constitute the altered volcanic rock and thus could be the metamorphic fluid existing when the present minerals of the rock formed. Although the water is supersaturated with respect to many clays, they cannot precipitate because the water is supersaturated with respect to the minerals now in the rock, and hence a free-energy barrier exists to clay-forming reactions. Thus, the minerals found and the water described can coexist indefinitely with no further reaction possible. If, however, the brine is removed and fresh (meteoric) water enters the rock, the calcite-low albite pair will be incompatible and will react to form laumontite (Barnes and others, 1978).


(Below - excerpted from Pg. 239+ ...)


THE 1980 ERUPTIONS OF MOUNT ST. HELENS, WASHINGTON

FUMAROLE ENCRUSTATIONS:
OCCURRENCE, MINERALOGY, AND CHEMISTRY

By TERRY E. C. KEITH, THOMAS J. CASADEVALL, and DAVID A. JOHNSTON


ABSTRACT

Fumaroles associated with the 1980 eruptive activity of Mount St. Helens occur (1) within the crater, where heat and fluids may be derived directly from magma and from crustal rocks in contact with the rising magma, and (2) as rootless fumaroles in the flowage deposits, where heat and fluids are derived locally from within the deposits. Much of the encrustation material was deposited at temperatures less than 250°C as noncrystalline yellowish films on ash particles and rock fragments and as encrustations around fumarole vents. Encrustations are mostly red, orange, yellow, and white. They begin to crystallize during cooling and dehydration immediately after deposition. Common mineral phases are sulfur, gypsum, halotrichite, and hematite. Less common phases are sal ammoniac, thenardite, glauberite, anhydrite, melanterite, alunite, and halite. Numerous unstable and poorly crystalline phases in process of dehydration and crystallization are under study. The major chemical components making up the fumarole deposits are Cl, F, H2O, SO4, Fe, Al, Ca, Na, K, and S.
 

INTRODUCTION

A fumarole is a vent that emits only gases and vapor. Encrustations are the colorful yellow, orange, red, and white deposits that generally surround fumaroles. Sublimate, a term often used for these encrustations, refers specifically to a solid phase deposited directly from a gaseous state without going through a liquid phase; the term is applicable to most encrustations, but not all.

Our study of fumaroles at Mount St. Helens focuses on the occurrence and distribution of different kinds of fumaroles and the chemistry and mineralogy of the encrustations. Reactions and products of hydrothermal alteration associated with the 1980 activity (Dethier and others, this volume) are not considered here.
 

ACKNOWLEDGMENTS

Field studies were by T. E. C. Keith and T. J. Casadevall, and by D. A. Johnston, who collected the first deposits from the summit crater on April 23 and analyzed the leachates. Identifications of mineral phases and chemical analyses were made by T. E. C. Keith, N. L. Nehring, T. S. Presser, D. P. Dethier, and D. R. Pevear.
 

METHODS

Temperatures of fumaroles were measured at the hottest accessible place in each vent. Gas and encrustation samples were collected simultaneously at several sites (see Casadevall and Greenland, this volume). The encrustation samples were sealed in plastic bags in the field until ready for laboratory study by X-ray diffraction (XRD) and scanning electron microscope (SEM). An energy dispersive X-ray analyzing system (EDAX) was used on the SEM to determine qualitatively most of the chemical components (most cations, Cl, and S) of the encrustation phases. Some soluble phases may have dissolved in water which condensed in the plastic bags. The hy-dration states of aluminum chloride, aluminum sulfate (± iron), calcium sulfate, and iron chloride probably changed somewhat during study. The color of some encrustations has changed from pale green (ferrous iron), to yellow, to orange, and finally to pale brownish red, indicating that iron in these hydrated phases oxidized after collection. Not all crystalline phases have yet been identified; however, the common morphologies and mineral phases have been determined by SEM and XRD.
 

FUMAROLES AT MOUNT ST. HELENS

Fumaroles at Mount St. Helens occur (1) within the crater, (2) on flowage deposits of the May 18 eruption and on more recent pyroclastic deposits, and (3) on the May 18 blast deposit (fig. 132). The fumaroles within the crater may be connected directly with a magmatic source of gas and heat. Fumaroles on the flowage deposits and on the blast deposit are termed "rootless" because they are not connected directly to a magmatic source of heat or gas.

Prior to 1980, Mount St. Helens exhibited little thermal activity. Phillips (1941) reported weak fumarolic activity (T = 88°C) at The Boot, at 2,740 m elevation on the north flank. A second thermal area at approximately 2,740 m elevation on the southwestern flank of the volcano (T = 89°C) was reported by Friedman and Frank (1977). Both thermal areas were destroyed on May 18.
 

FUMAROLES WITHIN THE CRATER

Within the crater, fumaroles occur (1) on the surface and at margins of successive dacite domes, (2) in cracks of the tephra blanket adjacent to the dome (fig. 133), and (3) along the intersection of the crater wall and the floor. Types 1 and 3 were not accessible during our sampling. Fumaroles of type 2 were studied on September 16 and 25 during visits into the crater.

The first dome, initially observed on June 15, was partially destroyed on July 22 (Moore and others, this volume). A second dome appeared in the crater following the eruption of August 7; a tephra blanket surrounded this dome and covered remnants of the June dome. Cracks in the tephra blanket, first observed on September 8, radiated northeast, north, and northwest from the dome. The cracks were as much as 50 cm wide, and many opened appreciably between visits on September 16 and 25. Incandescent rock, probably of the June dome, was locally visible in the cracks, and temperatures in them ranged from less than 200° to 838° C. Gases responsible for the deposition of encrustations were also probably derived from the June dome.

In the hottest (northeast) fracture, the crack walls contained no encrustation coatings but had apparently been slightly oxidized to a reddish, friable rubble. Yellow encrustation material was abundant on the surface a few centimeters outward from the cracks (fig. 133). This material is noncrystalline and is composed of Al, Cl, Fe, Ca, S, and H2O. Dehydration cracks developed (fig. 134), and blades of a crystalline material (Cl, Al, Fe, S, Ca, + water) began to form (fig. 135), finally resulting in a fuzzy bladed coating (fig. 136). Native sulfur was rarely observed as crystals on the ground surface adjacent to major cracks.

Deposition of a sublimate film from fumaroles within the crater began at temperatures below about 250°C. Rapid cooling of the almost colorless vapor produced a pale-yellowish-brown stain on crack walls. The stain did not obscure the textures of ash or rubble in the crack (fig. 133A). This stain material is soluble in water, has a high Cl-1 content (N. L. Nehring, written commun., 1980), and appreciable Fe+3, F-1, SO4-2, and Al (T. S. Presser, written commun., 1980).

Volcanic ash collected by David Johnston from the summit crater on April 23, 1980, was coated with similar yellowish film. Field analysis of the leachate of this film material showed appreciable Cl-1 and SO4-2. SEM study showed only ash particles, but EDAX analyses of the particle surfaces showed high Fe and Cl content, which must have been in some material forming very thin coatings on the ash particles. Scarce gypsum crystals had formed on the surface of one rock associated with the yellow deposit.
 

ROOTLESS FUMAROLES

Locations of rootless fumaroles on the flowage deposits were controlled by features such as preemption surface drainage, contrasting permeability of flowage deposits, and posteruption fractures produced by cooling or by settling of flowage deposits. Most rootless fumaroles that were active more than a few days were associated with pyroclastic flows that extended from north of the crater to Spirit Lake or with the debris-avalanche deposits in the North Fork Toutle River east of the mouth of Coldwater Creek (fig. 132).

Organic material (tree trunks, branches, and needles) is common in the flowage deposits of May 18. Where the deposits were hot, this material was distilled to varied products with sweet, turpentinelike odors. These distillates mostly escaped from individual small fumaroles or rows of fumaroles, and the ash overlying the organic material was discolored or coated by
 

brownish-red material. When temperatures were high enough, the trees smoldered or burned. As temperatures decreased, fumaroles over buried trees became fertile places for growth of fungi, algae, and, eventually, new plants.
 

PYROCLASTIC ROWS

Each pyroclastic flow had associated fumarolic activity. Temperatures were as high as ~850°C in these flows (Banks and Hoblitt, this volume), but fumarolic encrustations do not appear to have formed until the near-surface zone (less than 1-m depth) cooled to about 250°C or less. Of the pyroclastic flows examined (5/18, 5/25, 6/12, 7/22, 8/7), only the flow of June 12 contained solfataric fumaroles (fig. 137), distributed evenly over its surface at roughly 1- to 1.5-m spacing. These solfataras developed within a day of emplacement of the flow and persisted for several weeks before sulfur deposition declined. Gases from these fumaroles consist mostly of air and steam (Casadevall and Greenland, this volume).

Encrustations at fumaroles on pyroclastic flows are typically crusted with nearly white deposits, tinted with reddish iron oxides or hydroxides. Most contain an assemblage of gypsum and (or) anhydrite, iron oxide (hematite) or iron hydroxide, and native sulfur. Low-temperature fumaroles on the pyroclastic flows are yellow, as they are coated with native sulfur (fig. 137).

Iron leached from mafic material in dacitic ash is precipitated as an orange to red coating on the material through which the vapor passes. The red iron-rich coatings are deposited at high temperatures, usually during the initial stages of fumarolic activity (fig. 138). Metallic trace elements are also present in the dark-red coating from sample MSH 5-29-80-14 (T = 141°C; table 18). At high temperatures this reddish material is hematite; at lower temperatures it is amorphous iron hydroxide (fig. 139). Yellow encrustations (table 18) deposited over the dark-red material contain much lower concentrations of metallic trace elements, especially Ag, B, Ba, Cu, Zn, Zr, and Ga. Fumaroles 11 and 12, near the west edge of the May 18 pyroclastic flow, also exhibit this type of deposit. Anhydrite needles partly coated with anhedral blobs of alunite (probably natroalunite, fig. 140) form a later white deposit on iron oxide associated with fumarole 12 (now buried).
 

BLAST DEPOSIT

Rootless fumaroles in the blast deposit generally had temperatures below 150° C and were most common within a few kilometers of the crater, where the blast deposit is thickest. Feeble steaming at such fumaroles generally lasted only a few days to a few weeks, probably because the blast deposit was thin and cooled rapidly.
 

DEBRIS AVALANCHE

The debris avalanche is composed of material from the pre-May 18 edifice of Mount St. Helens mixed with sparse gray dacite from the 1980 cryptodome (Voight and others, this volume). These blocks of gray dacite showed little alteration or vesiculation, suggesting that they were not the major source of the volatiles responsible for the encrustations around the rootless fumaroles on the debris avalanche. Fumaroles on the debris avalanche had maximum measured temperatures of 125° to 150°C and cooled with time (fig. 141).

Fumarole 6, from the debris avalanche (fig. 141), was sampled on July 1, 1980, when the maximum temperature was 94° C. The encrustations consisted of an orange to yellow-orange deposit in the hottest area, grading outward to a greenish colloform deposit, surrounded by a zone of abundant white, gelatinous colloform material. A dark-gray outer zone resulted simply from water wetting the light-gray dacite ash. When the same fumarole was resampled on September 16, 1980, the maximum temperature was 69°C, and almost all orange and yellow color was gone (fig. 141B). The configuration of the fumarole was the same, however, and the encrustations consisted almost entirely of white colloform gypsum. The outer limit was still dark gray because of moisture. The yellow to orange material is mostly poorly crystalline and consists of S and Al with or without Cl, Fe, and Ca (fig. 142). As dehydration cracks develop in the material, hydrous calcium sulfate (containing much more water than gypsum) crystallizes (fig. 143). If dehydration continues, the stable product seems to be gypsum (fig. 144). Other phases that ultimately crystallize as the system cools are halotrichite (fig. 145) and hydrated aluminum sulfate. Native sulfur crystallizes on some deposits of this type as cooling continues, but little sulfur is present in fumarole deposits on the debris avalanche. The yellowish deposits consist largely of gypsum covered with a thin yellow coating, which seems to be non-crystalline and composed of iron and chloride with or without sulfate.
 

DISCUSSION

Fumaroles at Mount St. Helens apparently evolve in a predictable chemical and mineralogical pattern. For fumaroles with temperatures below about 250°C, most encrustations are white to yellowish orange and are first deposited as thin, noncrystalline deposits on rock fragments. Continued deposition results in a deposit of amorphous, often gelatinous material, typically colloform in appearance. With decreasing temperature and time, these deposits begin to crystallize and dehydrate through a series of unstable phases. Some phases are water soluble and easily leached by rain or surface drainage. The most stable phases that remain are gypsum, anhydrite, sulfur, hematite, and iron hydroxides. All minerals identified from Mount St. Helens fumaroles to date (table 19; BELOW) have been found previously as fumarole encrustations. (See Stoiber and Rose, 1974, for an excellent review.) The principal anions identified are Cl-1 and SO4-2, and the principal cations are Fe+2, Fe+3, Al+3, Na+, Ca+2, and K+; minor constituents are not yet known. Sulfur is the only element found in the native state. Nearly all phases are hydrous, but the extent of hydration is still under study.

Most encrustations are deposited from fumaroles with temperatures below 250°C. In general, fumaroles on the debris avalanche were initially cooler (less than 100°C) than those on the pyroclastic flows and in the crater. This difference in temperature is reflected in the mineralogy of the encrustations: those from the pyroclastic flows tend to have hematite; native sulfur and gypsum occur in both types of fumaroles; the higher temperature encrustations typically contain abundant chlorides and sulfates of Ca, Fe, and Al; and the hottest fumaroles adjacent to the dome entirely lack encrustations. These data support the observations of Stoiber and Rose (1974, p. 513), who found that encrustations deposited at high temperatures are generally less abundant than those deposited at lower temperatures.

Most fumarolic encrustations at Mount St. Helens are yellow to orangish yellow. Commonly, these are described by field observers as sulfur, but the color is generally due to hydrated chlorides and sulfates of Fe and Al. Only rarely did sulfur occur with a mineral other than gypsum. For example, fumarole 7, in the debris avalanche, had cooled to the point where it no longer deposited chloride-bearing minerals, and sulfur was apparently deposited over the earlier chloride assemblage. In the hotter fumaroles in the crater area and on the pyroclastic flows, encrustations are commonly buff to white with patches of iron-rich reddish-brown material.

Studies of burning refuse piles at coal mines demonstrate that mineral assemblages reminiscent of volcanic sublimates can be produced by heating finegrained sedimentary rocks (Dunrud and Osterwald, 1980; Finkleman, 1978). Many elements (alkaline earths, halides, sulfur, metals) are easily leached from fine-grained sediments and volcanic rocks by hydrothermal solutions with neutral or slightly acidic pH (Ellis and Mahon, 1967). Thus, many requisite components of fumarolic encrustations on the debris-avalanche deposits may be derived by heating the older rock of Mount St. Helens in a water-rich environment. Much rock was already heated and partly altered in the pre-May 18 hydrothermal system, and water from streams, marshes, and lakes could become an effective hydrothermal fluid capable of leaching cations and anions from rocks of the debris avalanche. Fumarolic encrustations could form following cooling of this fluid upon reaching the ground surface.

White and Waring (1963) pointed out the problems of determining which components of fumarolic encrustations were precipitated from vapor and which were derived from acid attack on surrounding rock particles. Our studies are continuing on this problem.
 



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